2-氯氯苯基氯,1-氯-2-(氯甲基)苯,α,2-二氯甲苯；2-氯氯苯基氯；1-氯-2-(氯甲基)苯；α,2-二氯甲苯
CAS 611-19-8
CHLOROBENZYL CHLORIDES
① 化学品基本信息
化学品名称
2-氯氯苯基氯,1-氯-2-(氯甲基)苯,α,2-二氯甲苯；2-氯氯苯基氯；1-氯-2-(氯甲基)苯；α,2-二氯甲苯
英文名称
CHLOROBENZYL CHLORIDES
CAS号
611-19-8
法规目录列入情况 命中 1 项
危险货物品名表
② 标签要素
危险性类别
严重眼损伤/眼刺激,类别2A,特异性靶器官毒性-一次接触,类别3（呼吸道刺激，麻醉效应）,特异性靶器官毒性-反复接触,类别1,危害水生环境-急性危害,类别1,危害水生环境-长期危害,类别1
GHS警示词
危险
GHS分类来源
自分类
象形图
GHS07
GHS08
GHS09
危险性说明
H319:造成严重眼刺激H335:可能引起呼吸道刺激H336:可能引起昏昏欲睡或眩晕H372:长时间或反复接触（如果可确证无其他接触途径引起该危害，说明接触途径）对器官造成伤害（如果已经知道，说明所受损害的器官）H410:对水生生物毒性极大并具有长期持续影响
③ 理化特性
外观与性状
无色液体，有刺鼻气味。
熔点（℃）
-17
沸点/沸程（℃）
213
相对蒸气密度（空气=1）
5.5
饱和蒸气压（kPa）
0.02（20℃）
辛醇/水分配系数（LogKow）
3.32
闪点（℃）
91
自燃温度（℃）
634
溶解性
难溶或不溶
密度
1270（20℃）
④ 危害信息
燃烧与爆炸危险性
Insoluble in water. Slowly reacts with water to form hydrochloric acid(hydrogen chloride).,Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. (ERG, 2016)
活性反应
Halogenated aliphatic compounds, such as CHLOROBENZYL CHLORIDE, are moderately or very reactive. Halogenated organics generally become less reactive as more of their hydrogen atoms are replaced with halogen atoms. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
禁配物
No information available.
中毒表现
Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. (ERG, 2016)
职业接触限值
燃烧时，生成一氧化碳。与强氧化剂发生反应。
环境危害
该物质对水生生物有极高毒性。强烈建议不要让该化学品进入环境。
⑤ 应急处置措施
急救措施
新鲜空气，休息。如果感觉不舒服，需就医。漱口。不要催吐。如果感觉不舒服，给予医疗护理。冲洗，然后用水和肥皂清洗皮肤。如果皮肤刺激发生，给予医疗护理。用大量水冲洗(如可能易行，摘除隐形眼镜)。
泄漏应急处理
Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2016),Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above.FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
灭火方法
If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
⑥ 安全技术说明书
该物质在登记平台未登记 SDS 文件。
平台未登记 SDS
数据来源：应急管理部化学品登记中心 · 国家危险化学品安全公共服务互联网平台（whpdj.mem.gov.cn）